[rael-science] Stanford's touch-sensitive plastic skin heals itself‏

วันศุกร์ที่ 16 พฤศจิกายน พ.ศ. 2555

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The Raelian Movement
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http://news.stanford.edu/news/2012/november/healing-plastic-skin-111112.html

Stanford Report, November 11, 2012

Stanford's touch-sensitive plastic skin heals itself

A team of Stanford chemists and engineers has created the first synthetic material that is both sensitive to touch and capable of healing itself quickly and repeatedly at room temperature. The advance could lead to smarter prosthetics or resilient personal electronics that repair themselves.
BY KELLY SERVICK
L.A. CiceroA small piece of the self-healing material is sliced with a scalpel. The researchers say the material repairs itself in about 30 minutes.
A small piece of the self-healing material is sliced with a scalpel. The researchers say the material repairs itself in about 30 minutes.
Nobody knows the remarkable properties of human skin like the researchers struggling to emulate it. Not only is our skin sensitive – sending the brain precise information about pressure and temperature – but it also heals efficiently to preserve a protective barrier against the world. Combining these two features in a single synthetic material presented an exciting challenge for Stanford chemical engineering Professor Zhenan Baoand her team.
Now, they have succeeded in making the first material that can both sense subtle pressure and heal itself when torn or cut. Their findings will be published Nov. 11 in the journal Nature Nanotechnology.
In the last decade, there have been major advances in synthetic skin, said Bao, the study's principal investigator, but even the most effective self-healing materials had major drawbacks. Some had to be exposed to high temperatures, making them impractical for day-to-day use. Others could heal at room temperature, but repairing a cut changed their mechanical or chemical structure, so they could heal themselves only once. Most important, no self-healing material was a good bulk conductor of electricity, a crucial property.
"To interface this kind of material with the digital world, ideally you want it to be conductive," said Benjamin Chee-Keong Tee, a researcher on the project.

A new recipe

The researchers succeeded by combining two ingredients to get what Bao calls "the best of both worlds" – the self-healing ability of a plastic polymer and the conductivity of a metal.
They started with a plastic consisting of long chains of molecules joined by hydrogen bonds – the relatively weak attractions between the positively charged region of one atom and the negatively charged region of the next.
"These dynamic bonds allow the material to self-heal," said Chao Wang, another member of the research team. The molecules easily break apart, but then when they reconnect, the bonds reorganize themselves and restore the structure of the material after it gets damaged, he said. The result is a bendable material, which even at room temperature feels a bit like saltwater taffy left in the fridge.
To this resilient polymer, the researchers added tiny particles of nickel, which increased its mechanical strength. The nanoscale surfaces of the nickel particles are rough, which proved important in making the material conductive. Tee compared these surface features to "mini-machetes," with each jutting edge concentrating an electrical field and making it easier for current to flow from one particle to the next.
The result was a polymer with uncommon characteristics. "Most plastics are good insulators, but this is an excellent conductor," Bao said.

Bouncing back

The next step was to see how well the material could restore both its mechanical strength and its electrical conductivity after damage.
L.A. CiceroPost doctoral scholar Chao Wang cuts through a sample of the self-healing plastic material developed in the Bao lab.
Post doctoral scholar Chao Wang cuts through a sample of the self-healing plastic material developed in the Bao lab.
The researchers took a thin strip of the material and cut it in half with a scalpel. After gently pressing the pieces together for a few seconds, the researchers found the material gained back 75 percent of its original strength and electrical conductivity. The material was restored close to 100 percent in about 30 minutes. "Even human skin takes days to heal. So I think this is quite cool," Tee said.
What's more, the same sample could be cut repeatedly in the same place. After 50 cuts and repairs, a sample withstood bending and stretching just like the original.
The composite nature of the material created a new engineering challenge for the team. Bao and her co-authors found that although nickel was key to making the material strong and conductive, it also got in the way of the healing process by preventing the hydrogen bonds from reconnecting as well as they should.
For future generations of the material, Bao said, the team might adjust the size and shape of the nanoparticles, or even the chemical properties of the polymer, to get around this trade-off.
Nonetheless, Wang said the extent of these self-healing properties was truly surprising: "Before our work, it was very hard to imagine that this kind of flexible, conductive material could also be self-healing."

Sensitive to the touch

The team also explored how to use the material as a sensor. For the electrons that make up an electrical current, trying to pass through this material is like trying to cross a stream by hopping from stone to stone. The stones in this analogy are the nickel particles, and the distance separating them determines how much energy an electron will need to free itself from one stone and move to another.
Twisting or putting pressure on the synthetic skin changes the distance between the nickel particles and, therefore, the ease with which electrons can move. These subtle changes in electrical resistance can be translated into information about pressure and tension on the skin.
Tee said that the material is sensitive enough to detect the pressure of a handshake. It might, therefore, be ideal for use in prosthetics, Bao added. The material is sensitive not only to downward pressure but also to flexing, so a prosthetic limb might someday be able to register the degree of bend in a joint.
Tee pointed out other commercial possibilities. Electrical devices and wires coated in this material could repair themselves and get electricity flowing again without costly and difficult maintenance, particularly in hard-to-reach places, such as inside building walls or vehicles.
Next up, Bao said, is the team's goal to make the material stretchy and transparent, so that it might be suitable for wrapping and overlaying electronic devices or display screens.
Ranulfo Allen, a graduate student in chemical engineering, also contributed to this research. The research was supported by the Air Force Office of Scientific Research.
Kelly Servick is a science-writing intern working for the Stanford University School of Engineering.
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which in this case was very clear: I support decriminalizing all drugs,
as it is stupid to throw depressed and sad people (as only depressed and
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The same applies to the freedom of expression which must be absolute.
That does not mean again of course that I agree with anti-Jews,
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-- 
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"Ethics" is simply a last-gasp attempt by deist conservatives and
orthodox dogmatics to keep humanity in ignorance and obscurantism,
through the well tried fermentation of fear, the fear of science and
new technologies.
 
There is nothing glorious about what our ancestors call history, 
it is simply a succession of mistakes, intolerances and violations.
 
On the contrary, let us embrace Science and the new technologies
unfettered, for it is these which will liberate mankind from the
myth of god, and free us from our age old fears, from disease,
death and the sweat of labour.
 
Rael
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WARNING FROM RAEL: For those who don't use their intelligence at its
full capacity, the label "selected by RAEL" on some articles does not
mean that I agree with their content or support it. "Selected by RAEL"
means that I believe it is important for the people of this planet to
know about what people think or do, even when what they think or do is
completely stupid and against our philosophy. When I selected articles
in the past about stupid Christian fundamentalists in America praying
for rain, I am sure no Rael-Science reader was stupid enough to
believe that I was supporting praying to change the weather. So, when
I select articles which are in favor of drugs, anti-semitic,
anti-Jewish, racist, revisionist, or inciting hatred against any group
or religion, or any other stupid article, it does not mean that I
support them. It just means that it is important for all human beings
to know about them. Common sense, which is usually very good among our
readers, is good enough to understand that. When, like in the recent
articles on drug decriminalization, it is necessary to make it
clearer, I add a comment, which in this case was very clear: I support
decriminalizing all drugs, as it is stupid to throw depressed and sad
people (as only depressed and sad people use drugs) in prison and ruin
their life with a criminal record. That does not mean that there is
any change to the Message which says clearly that we must not use any
drug except for medical purposes. The same applies to the freedom of
expression which must be absolute. That does not mean again of course
that I agree with anti-Jews, antisemites, racists of any kind or
anti-Raelians. But by knowing your enemies or the enemies of your
values, you are better equipped to fight them. With love and respect
of course, and with the wonderful sentence of the French philosopher
Voltaire in mind: "I disapprove of what you say, but I will defend to
the death your right to say it".